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AN-H-102

Determination of Hypochlorite by Titration with Ammonium Ion


Summary

Hypochlorite ions react with bromide ions to form hypobromite ions, which in turn rapidly oxidize ammonium ions to nitrogen. Hypobromite reacts more rapidly with ammonium than hypochlorite, and is formed in situ (Vogel, 1961). The titration is carried out with in a solution containing bromide and bicarbonate.
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Metrohm AG

Ionenstrasse
9100 Herisau

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